Anatase Rutile Nanocrystals

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Ligand-free rutile and anatase TiO2 nanocrystals as ...

2.2 Synthesis of the anatase/rutile TiO2 nanocrystals Anatase/rutile TiO 2 nanocrystals were synthesized by using a developed synthetic method with slight modi cation.32 (1) Synthesis of rutile nanocrystals: aqueous solutions of TiCl 3 ( 20%, 1.6 mL) and SnCl 4 (0.5 M, 1.0 mL) were mixed with ethanol (60 mL) in a glass bottle. A er being sealed with par-

Ligand-free rutile and anatase TiO2 nanocrystals as ...

Ligand-free rutile and anatase TiO 2 nanocrystals have been synthesized through a hydrolytic sol–gel reaction. The morphology, crystal structure, elemental composition and band structure of the obtained nanocrystals are characterized by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy and UV-visible absorption spectroscopy. These two kinds of nanocrystals …

Anatase-rutile phase transformation and photocatalysis in ...

01.10.2020· Likewise, a widely accepted concept is that rutile nucleation occurs at the surfaces or interfaces of aggregated anatase nanocrystals with ease than in the bulk of the particle . XRD analysis in the present study revealed that the onset temperature of anatase to rutile transformation is 300 °C. The crystalline, smaller sized particles in the as-prepared sample might have facilitated the speedy anatase to rutile …

Study on the anatase to rutile phase transformation and ...

15.06.2010· We developed a route to synthesize rutile TiO(2) nanocrystals (NCs) with the assistance of 1-butyl-3-methylimidazolium chloride (bmim(+)Cl(-)). The phase transformation from anatase to rutile phase was investigated, and a simple model to describe the phase transformation process was proposed considering that the nucleation and growth of rutile phase were determined by the aggregation manner of anatase …

Study on the Anatase to Rutile Phase Transformation and ...

We developed a route to synthesize rutile TiO2 nanocrystals (NCs) with the assistance of 1-butyl-3-methylimidazolium chloride (bmim+Cl−). The phase transformation from anatase to rutile phase was investigated, and a simple model to describe the phase transformation process was proposed considering that the nucleation and growth of rutile phase were determined by the aggregation manner of anatase …

Structure-Reactivity Relationships of Anatase and Rutile ...

A comprehensive analysis of structural-reactivity relations on TiO2 nanocrystals is presented. Using an interplay between TEM, X-ray diffraction and vibrational spectroscopy of well-defined anatase and rutile TiO2 nanocrystals correlations between the adsorbate structure of formic acid and the corresponding photo-induced decomposition rate are described.

Anatase-rutile phase transformation and photocatalysis in ...

XRD analysis reveals a phase pure anatase structure for the as-prepared sample and anatase-rutile mixed-phase for annealed TiO 2 nanocrystals. UV–visible diffuse reflectance and Fourier transform infrared spectroscopic measurements also confirm the formation of anatase-rutile mixed phase for annealed samples. Micro-Raman spectra recorded for three different excitation wavelengths suggest the formation of rutile phase in the interior of the anatase nanoparticles …

Synthesis of Anatase TiO2 Nanocrystals with Defined ...

17.04.2019· Rutile/anatase TiO 2 nanocrystals with various morphologies and exposed crystal facets, have been successfully synthesized by a facile hydrothermal strategy in the absence of fluorine and organic capping surfactants. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution ...

Study on the anatase to rutile phase transformation and ...

15.06.2010· Study on the anatase to rutile phase transformation and controlled synthesis of rutile nanocrystals with the assistance of ionic liquid. Ding K(1), Miao Z, Hu B, An G, Sun Z, Han B, Liu Z. Author information: (1)Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. We developed a route to synthesize rutile TiO(2 ...

Structure-Reactivity Relationships of Anatase and Rutile ...

A comprehensive analysis of structural-reactivity relations on TiO2 nanocrystals is presented. Using an interplay between TEM, X-ray diffraction and vibrational spectroscopy of well-defined anatase and rutile TiO2 nanocrystals correlations between the adsorbate structure of formic acid and the corresponding photo-induced decomposition rate are described.

(PDF) Micro Strain and Morphological Studies of Anatase ...

Nanocrystals of Titanium dioxide were prepared via sol-gel and solvothermal method. They were characterized by X-ray diffraction and Scanning Electron Microscopy studies. The anatase and rutile phase reflections of the Titanium dioxide nanocrystals

Synthesis of Anatase TiO2 Nanocrystals with Defined ...

17.04.2019· Rutile/anatase TiO 2 nanocrystals with various morphologies and exposed crystal facets, have been successfully synthesized by a facile hydrothermal strategy in the absence of fluorine and organic capping surfactants. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution ...

Structural Properties, Lattice Strain and Transformation ...

Vol. 25, No. 1 (2013) Properties of Anatase-Type TiO 2 Nanocrystals to Rutile in TiO 2-SiO 2 Composite 357. XRD patterns of nano-TiO 2 in rutile and anatase phases and their thermal treatment (calcined temperature) at 300, 500, 700 and 900 ºC are displayed in Figs. (3-13). Fig. (3-8) are the patterns of samples with specific TiO 2 content in TiO 2-SiO 2 composite, but different calcined ...

Photocatalytic Studies of Anatase and Rutile phase TiO2 ...

25.08.2015· Photocatalytic Studies of Anatase and Rutile phase TiO2 Nanocrystals Prepared via Solvoth Published on Aug 25, 2015 Nanocrystals of TiO2 photocatalyst have been synthesized by solvothermal method.

Controllable One-Step Synthesis of Mixed-Phase TiO2 ...

01.05.2021· In this study, the novel mixed-phase TiO 2 nanocrystals (s-TiO 2) with nearly equivalent anatase/rutile ratio were fabricated in the reagent of sec-butanol at the relatively low temperature of 80 °C by using a facile one-step condensing reflux method.The photocatalytic water splitting hydrogen production performance of s-TiO 2 nanocrystals is close to that of commercial TiO 2 (P25), and its ...

Why is anatase a better photocatalyst than rutile? - …

10.02.2014· The prototypical photocatalyst TiO2 exists in different polymorphs, the most common forms are the anatase- and rutile-crystal structures. Generally, anatase is more active than rutile, but no ...

Preparation of TiO2 Anatase Nanocrystals by TiCl4 ...

15.06.2011· Depending on the acidity, the hydrolysis temperature, and the calcination temperature, rhombic anatase nanocrystals sizes in the range of 10 nm to 50 nm were obtained. In the additive of sulfuric acid, Raman spectra and electron diffraction confirmed that the nanoparticles are composed of anatase TiO2. No other titania phases, such as rutile or ...

Academics in Sol−Gel Synthesis and Hydrothermal …

View Academics in Sol−Gel Synthesis and Hydrothermal Processing of Anatase and Rutile Titania Nanocrystals on Academia.edu.

Selective Catalytic Reduction of NO Using Phase-Pure ...

We demonstrate a facile selective synthesis of phase-pure anatase, rutile, and brookite nanocrystal polymorphs of titania (TiO 2 ) using a benign hydrothermal treatment of an industrial grade TiOSO 4 precursor. Acetic acid (CH 3 COOH) is used for the synthesis of anatase, … Selective Catalytic Reduction of NO Using Phase-Pure Anatase, Rutile, and Brookite TiO 2 Nanocrystals Inorg Chem. …

CHARACTERIZING THE MECHANISM OF NANOCRYSTALLINE ANATASE …

HRTEM images of anatase and rutile nanocrystals in the inset of (a) and (b), respectively. Insets show the images of the region labeled with white boxes. ..... 52 Figure 3.3 Figures present the change in phase content of the samples aged at 200 °C (a and b), 225 °C (c and d), and 250 °C (e and f) for different time periods. pH 1 was used in all suspensions. ..... 54 Figure 3.4 The plots ...

Structure-Reactivity Relationships of Anatase and Rutile ...

A comprehensive analysis of structural-reactivity relations on TiO2 nanocrystals is presented. Using an interplay between TEM, X-ray diffraction and vibrational spectroscopy of well-defined anatase and rutile TiO2 nanocrystals correlations between the adsorbate structure of formic acid and the corresponding photo-induced decomposition rate are described.

Synthesis of Anatase TiO2 Nanocrystals with Defined ...

17.04.2019· Rutile/anatase TiO 2 nanocrystals with various morphologies and exposed crystal facets, have been successfully synthesized by a facile hydrothermal strategy in the absence of fluorine and organic capping surfactants. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and high-resolution ...

Size‐Dependent Surface Activity of Rutile and Anatase …

29.02.2012· Size-Dependent Surface Activity of Rutile and Anatase TiO 2 Nanocrystals: Facile Surface Modification and Enhanced Photocatalytic Performance Dr. Guolei Xiang, Department of Chemistry, Tsinghua University, Beijing 100084 (P.R. China) Search for more papers by this author. Dr. Yang-Gang Wang, Department of Chemistry, Tsinghua University, Beijing 100084 (P.R. China) …

Structural Properties, Lattice Strain and Transformation ...

Vol. 25, No. 1 (2013) Properties of Anatase-Type TiO 2 Nanocrystals to Rutile in TiO 2-SiO 2 Composite 357. XRD patterns of nano-TiO 2 in rutile and anatase phases and their thermal treatment (calcined temperature) at 300, 500, 700 and 900 ºC are displayed in Figs. (3-13). Fig. (3-8) are the patterns of samples with specific TiO 2 content in TiO 2-SiO 2 composite, but different calcined ...

Preparation of TiO2 Anatase Nanocrystals by TiCl4 ...

15.06.2011· Depending on the acidity, the hydrolysis temperature, and the calcination temperature, rhombic anatase nanocrystals sizes in the range of 10 nm to 50 nm were obtained. In the additive of sulfuric acid, Raman spectra and electron diffraction confirmed that the nanoparticles are composed of anatase TiO2. No other titania phases, such as rutile or ...

Why is anatase a better photocatalyst than rutile? - …

10.02.2014· The prototypical photocatalyst TiO2 exists in different polymorphs, the most common forms are the anatase- and rutile-crystal structures. Generally, anatase is more active than rutile, but no ...

Synthesis of Titanium Dioxide Nanocrystals with Controlled ...

11.10.2013· polymorphs including anatase, rutile, brookite and TiO 2(B) by solvothermal treatment of water-soluble titanium complexes is described with a special focus on their morphological control. The utilization of water- soluble titanium complexes as a raw material allowed us to employ various additives in the synthesis of TiO 2. As a result, the selective synthesis of the polymorphs, as well as ...

Academics in Sol−Gel Synthesis and Hydrothermal …

View Academics in Sol−Gel Synthesis and Hydrothermal Processing of Anatase and Rutile Titania Nanocrystals on Academia.edu.